AlegsaOnline.com Home Geography Toledo Province Toledo Province Author: Leandro Alegsa Creation date: November 13, 2022 en.wikipedia.org · CC BY 2.0 Province of Toledo (Spanish: Provincia de Toledo) is one of the provinces of Castile-La Mancha, in the center of Spain, near Madrid. The capital is Toledo and the biggest city is Talavera of the Queen. The population of the province is near 600,000.