In hydraulic fracturing, a fluid (frac fluid), which may also contain a proppant, is injected into a well, usually several hundred to a maximum of about 3000 metres deep. The fluid pressure reached in the area to be fractured must exceed the lowest stress present in the rock and the tensile strength of the rock in order to fracture the rock. If this is the case, the fluid pushes the rock apart (tensile fracture). Normally, the horizontal components of the stress field are smaller than the vertical component because the vertical component - the lithostatic pressure resulting from the weight of the overlying rock layers - increases continuously with depth and is thus the largest of the principal stress components below a certain depth. Thus, tensile fractures caused by fracking occur predominantly as mostly near-vertical fracture surfaces that open in the direction of the smallest horizontal principal stress and thus propagate in the direction of the largest horizontal principal stress. On a smaller scale, the stress field can be oriented significantly differently, e.g. due to additional tectonic stresses.
After fracturing the formation, the injection pressure is reduced and most of the injected fluid, which is still under the pressure of the rock layer, flows back. This flowback water is called backflow or flowback. The added proppant remains in the fractures and keeps them open. Additives of the frac fluid also partly remain in the rock due to adhesion effects at the fluid-rock boundaries.
In order to optimally extract the dissolved gas, several wells are drilled from a drilling starting point, often almost horizontally in depth, but in any case within the target formation. The deviated wells are guided precisely in the reservoir using the so-called directional drilling method. The drilling path is controlled during drilling with the aid of a MWD (measurement while drilling) measuring unit placed directly behind the drill bit (geo-steering).
The deviated wells are then fracked individually and in sections, adapted to the geological and geomechanical subsurface conditions, several times (12 to 16 times). The aim of this "multi-well pad" process is to exploit the gas in the target horizon as spatially as possible from a larger volume of the well environment tapped by the fracs. It is this process that has enabled the breakthrough to large-scale industrial use of frac technology. In contrast, some shale gas fields in the United States and elsewhere, such as the Jonah gas field in Upper Green Valley, Wyoming, were previously developed using single vertical, non-frac wells. This required six to eight wells per square mile (equivalent to two to three wells per square kilometer). Today's technology drastically reduces the number of wells per square kilometer and especially the number of drilling sites, whereby the possible length of the deviated well sections in particular determines the drilling site grid. Today, drilling site distances of 10 km are quite conceivable.
Fracfluids
Fracfluids are fluids that are injected into the well and create artificial fractures in the gas-bearing target formation at high pressure. With the help of certain conditioned frac fluids, various proppants are introduced into the pathways created by fracking in order to stabilize them for as long as possible and guarantee gas continuity. A distinction is made between foam-based, gel-based and so-called slickwater fluids. The main component of the highly viscous, gel-based frac fluids is usually water tempered with additives, to which mainly tempered sand and ceramic beads (proppants) are also added. Gel-based frac fluids are mainly used in clastic rocks such as sandstones (conventional reservoirs).
In contrast, so-called extremely low-viscosity slickwater fluids are mainly used in claystones (unconventional deposits), which are made extremely flowable by adding friction reducers. Slickwater fluids consist of 98-99 % water plus 1-1.9 % proppants and less than 1 % additives.
The composition of the additives is normally named by the drilling and service companies to the regulatory authorities, but kept secret from the public. In Germany, the individual additives must be approved in accordance with the requirements of water law as part of the approval process for the wells.
Examples of possible additives and the purpose of their use are:
| Additive | English designation | Realizations | Purpose |
| Supporting means | Proppant | Quartz sand, sintered bauxite, ceramic beads, e.g. coated with epoxy or phenolic resin | Keeping open and stabilising the cracks created during fracking |
| Gels, thickeners | Success Agent | Guar gum, cellulose polymers such as MC and carbohydrate derivatives | Increasing the viscosity of the frac fluid for better proppant transport |
| Foaming agent | Foam | CO2 or N2 and foaming agents: tertiary alkyl amine ethoxylates, coco-betaines or α-olefin sulphonates. | Transport and deposition of the propping agent |
| Deposition inhibitor | Scale inhibitor | Ammonium chloride, polyacrylates and phosphonates | Preventing the deposition and dissolution of poorly soluble mineral deposits in the borehole |
| Corrosion inhibitor | corrosion inhibitor | Methanol, isopropanol, ammonium salts, sulphites, (e.g. amine bisulphite) | Protection of facilities, equipment and drill string |
| Chain Breaker | Breaker | Sodium bromate, ammonium and sodium peroxodisulphate, enzymes | Reduction of the viscosity of gel-based frac fluids for better recovery of the fluids (destruction of the gel structure) |
| Biocides | Biocide | terpenes, glutaraldehyde, isothiazolinones such as chloromethylisothiazolinone | Prevention of bacterial growth and biofilms, prevention of hydrogen sulphide formation (desulphurisation) |
| Fluid Loss Additives | Fluid Loss Additives | Rinsing additives with thixotropic properties | Reduction of the outflow of the frac fluid into the surrounding rock |
| Friction reducer | friction reducer | Latex polymers, polyacrylamide, hydrogenated light petroleum distillates | Reduction of friction within the fluids |
| pH buffer | pH Control | Acetic acid, fumaric acid, potassium carbonate, borax, sodium acetate, sodium bicarbonate, sodium hydroxide | Buffer for adjusting the pH value |
| Clay stabilizers | clay stabilizer | Potassium salts, e.g. potassium chloride, ammonium salts | Prevention and reduction of swelling of clay minerals |
| Surfactants (wetting agents) | Surfactants | ethoxylated alkyl alcohols, nonylphenol ethoxylates | Reduction of the surface tension of the fluids to improve wettability |
| Acids | Acids | Hydrochloric acid | Cleaning of the perforated sections of the drill string from cement and drilling fluid |
| Hydrogen sulfide scavenger | H2S Scavenger | aromatic aldehydes | Removal of hydrogen sulphide (corrosion protection) |
| Crosslinker | Crosslinker | triethanolamine, sodium tetraborate, citrus terpenes, zirconyl chloride, borates, organic zirconium complexes | Cross-linking of gel formers, increase of viscosity |
| Solvent | Solvents | Ethylene glycol monobutyl ether, 1-propanol | |
| Temperature stabilizer | temperature stabilizer | Sodium thiosulfate | Prevention of gel decomposition at great drilling depths |
| Iron chelators | Iron Control | Citric acid, ethylenediaminetetraacetate | Prevention of precipitation of ferrous minerals in the target formation |
The composition of the frac fluids is determined separately for each well using decision matrices and/or computer programs and depends on the mineralogical-geological properties of the target horizon and the pressure and temperature conditions prevailing in the reservoir.
Clean fracking, on the other hand, refers to a new method of fracking in which only water, bauxite sand and starch are used.
Flowback and production water
Flowback water is the mud fluid that exits the surface of the wellbore during drilling and fracking until approximately 30 days later.
The water that is subsequently produced is composed of mud fluid, formation water (groundwater) and any dissolved gases and entrained solids therein and is referred to as production water. Approximately 20 to 50% of the frac fluid injected at depth is recovered as flowback water or with the production water and stored at the well site until disposal. The storage in open basins, which is common in some places in the American gas fields, cannot be approved in Germany. The containers in which the flowback or production water is stored are subject to water law requirements so that liquids are prevented from seeping into the ground.
The flowback and production water must be treated and processed in several stages before reuse or final disposal. First, the solids (cuttings) are separated at the well site in hydrocyclone plants, and the mud is disposed of. The recovered fluids, which are largely freed of solids, are usually transported by tanker trucks or through pipelines to a processing station. There, the oil phase, the remaining sludge and filtrate are separated in various tank farms with phase separators and filter systems. Depending on the hydrochemical properties, the residual water can either be mixed with fresh water and added back to the mud circuit or injected into approved injection wells in the margins of already developed or exploited hydrocarbon reservoirs. The light phase separated in these processes is further processed in refineries, and the filtrate is disposed of by certified companies.
In addition, various treatment methods, such as UV treatment, membrane filtration, coagulation and evaporation, are used to either reuse the frac fluids or reduce the amount to be disposed of.