Thermal efficiency (process efficiency)
Temperature
The upper limit for any thermal efficiency is the Carnot efficiency:
,
where
the lowest and
the highest temperature in Kelvin occurring in the process.
Power
The mechanical or thermal efficiency or process efficiency indicates the ratio of the mechanical power gained to the heat flow supplied in a heat engine, e.g. a steam turbine:

with η
as the thermal efficiency, with
(in watts) as the mechanical power gained, and with
(in watts) as the supplied heat flux.
Energy
If the specific heating energy of the fuel (
in kWh/kg) and the specific fuel consumption of the machine (
in kg/kWh) are known, the mechanical or thermal efficiency (power from heat) can be calculated:

Combustion efficiency
The firing efficiency (FTW) indicates the utilization of the heat resulting from the combustion of a fuel at nominal power. It only takes into account the heat loss due to cooling of the flue gases to ambient temperature. It is possible to evaluate the energy efficiency of a heat generator using this flue gas loss alone if all other losses are negligible. Until the end of the 20th century, this approximate calculation was common for heating systems; today, the system efficiency or annual utilization factor is considered.
The FTW is the difference of 1 (100 %) and the exhaust gas loss
:

Modern plants increase efficiency by lowering exhaust gas temperatures and recovering condensation heat from steam and hydrocarbons. They utilize the calorific value of a fuel, whereas in old plants only the calorific value could be used. High demands are made on the chimney system. Some of the exhaust gases have to be transported away actively (e.g. by a fan), as they are no longer warm enough to rise by themselves. The chimney is exposed to corrosive attack by the combustion residues dissolved in the condensed water (sooting). Under certain conditions, tar is also formed, which must be collected and returned to the combustion process.
Full condensing boilers, the air/flue gas system or the heating of ancillary rooms also use the latent residual heat of the flue gas below the return temperature of the normal heating system in the case of condensing boilers. It should be noted, however, that gases have a low heat storage capacity and that a higher monetary benefit could sometimes be achieved "for the same money" with better thermal insulation of the house or other energy-saving measures.
Heat dissipation as a result of the reaction enthalpies in the formation of nitrogen oxides or their reduction by lowering the combustion temperatures with the aid of porous burners or catalytic burners is not taken into account in the calculation method for combustion efficiency (which no longer reflects the state of the art and is therefore outdated).
Boiler efficiency
The boiler efficiency hK (%) is the ratio of nominal heat output as a percentage of the nominal heat load when measured in constant continuous operation at nominal heat output. Like the FTW, it also takes into account the exhaust gas loss, but in addition also the heat loss to the environment of the installation room.
Exergetic efficiency
The exergetic efficiency, also called isentropic efficiency, is mostly used to describe heat engines which do not only deliver mechanical or electrical energy but also useful heat. Here, the two different energy qualities (cf. with the 2nd law of thermodynamics) must be brought to a common denominator. Exergy stands here for the technical working capacity; isentropic processes do not change the entropy.
Thermal energy cannot be completely converted into other forms of energy (e.g. electrical energy, mechanical energy). The two terms anergy and exergy describe which part of the thermal energy can be converted into useful physical work (exergy) and which part must be released into the environment as unusable waste heat (anergy) in order to dissipate the entropy of the energy conversion. The following applies:

The generation of heat, even in a condensing boiler with nominal 100 % efficiency, is always associated with entropy production. Thus, low-temperature heat consists of a lot of anergy and little exergy. The exergy content of heat corresponds to the Carnot factor.
The efficiency of a real heat engine is always less than or equal to that of the ideal heat engine, the Carnot efficiency

with
as lower temperature (inferior) and
as upper temperature (superior).
The exergetic efficiency of an energy conversion relates all incoming and outgoing energy flows to the exergy content, i.e. the work capacity.

Gross and net efficiency
For thermal power plants in particular, a distinction is made between gross and net efficiency. Gross efficiency refers to the gross output
, i.e., the electrical output without taking into account self-consumers such as feedwater pumps:

(Where
is the mass flow rate of the supplied fuel and
is the heating value of the fuel).
Net efficiency, on the other hand, refers to the net power
, i.e., the electrical power after subtracting the power consumption of the self-consumers
:

In German-speaking countries, the net efficiency is given for power plants unless explicitly stated otherwise.
Plant efficiency and overall efficiency
If several machines and transformers work in series, their individual efficiencies are multiplied to the total efficiency η
of the plant, the plant efficiency.

Example:
Total efficiency: η
or 34 %.
In this example, it is assumed that the energy transfer between the individual machines is loss-free. If this is not the case, additional efficiencies of the energy transfer must be included in the calculation.
If the waste heat released during a thermal conversion process is used further, for example for air preheating, oil preheating or district heating, as is the case with combined heat and power plants (see table below), the efficiency of the plant is increased because part of the heat actually lost for the process can still be used.
Annual utilization rate
The annual efficiency is the annual average system efficiency over all operating cycles of a heat generator.
It enables a more realistic cost-benefit calculation for energy-saving measures than is possible with the approximate calculation of FTW. As even average houses consume less and less energy by improving insulation, the consideration of other losses becomes more and more important. These include heat loss from heat generators due to radiation, loss due to condensation of water in the fuel, heat required due to frequent starts of the heating system with poor efficiency in the start-up phase, low burner running time due to oversized boiler.
Even though modern individual devices of a heating system usually have an efficiency at rated power of over 90%, the annual efficiency amounts to only 60-80%, which is emitted by the radiator.
Standard utilization rate
The standard utilization factor incorporates the new technology of condensing boilers with modulating output control (part-load operation) through staged part-load operation points of 12.8%, 30.3%, 38.8%, 47.6%, and 62.6% of rated output.
The calculation is specified according to DIN 4702 part 8 for
- Heating mode,
- combined heating operation with, however, only about five percent share of hot water heating,
- Hot water heating.