What is the Diels–Alder reaction?

Q: What is the Diels–Alder reaction?


A: The Diels–Alder reaction (DA) is a chemical reaction between organic compounds which causes them to form a new six-sided compound called a cyclohexene.

Q: Who discovered the DA reaction?


A: The DA reaction was discovered by Otto Diels and Kurt Alder in 1928.

Q: What did they receive for their work on this reaction?


A: In 1950, they were given the Nobel Prize in Chemistry for their work on this reaction.

Q: What are cyclohexenes used for?


A: Cyclohexenes are used to make complex organic molecules. One of the first uses of the DA reaction was to make insecticides.

Q: How does a DA reaction create a hexagonal ring-shaped compound?


A: A compound with two double bonds which are one carbon atom apart from each other is joined to another compound with at least one double bond, creating a hexagonal ring-shaped compound.

Q: Are some DA reactions reversible?


A: Yes, some of the DA reactions are reversible and the breaking up of the cyclic system during this process is called retro-Diels–Alder.

Q: What catalysts can be used to speed up the DA Reaction?


A: Lewis acids such as AlCl3 and ZnCl2 can act as catalysts to speed up the DA Reaction.

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